Effect of an External Magnetic Field on the Hydrogen Reduction of Magnetite Nanoparticles in a Polymer Matrix

Author:

Chernavskii Petr123,Ozkan Sveta2ORCID,Karpacheva Galina2ORCID,Pankina Galina123,Perov Nikolai4ORCID

Affiliation:

1. Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia

2. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospect, 29, 119991 Moscow, Russia

3. Institute of Organic Chemistry N.D. Zelinsky, RAS, 119991 Moscow, Russia

4. Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow, Russia

Abstract

A hybrid electromagnetic nanomaterial, which is a matrix based on a conjugated polymer of poly-3-amine-7-methylamine-2-methylphenazine with dispersed magnetite nanoparticles immobilized on multi-walled carbon nanotubes, has been synthesized. In situ magnetometry was used to study the kinetics of the hydrogen reduction of Fe3O4 immobilized in the structure of a ternary nanocomposite in magnetic fields of different intensities. An increase in the magnetite reduction reaction rate with the formation of metallic iron nanoparticles at T=420∘C and at a magnetic field strength in the range of 60–3000 Oe was observed. The dependence of the degree of conversion of Fe3O4 on the magnetic field strength was established.

Publisher

MDPI AG

Subject

Materials Chemistry,Chemistry (miscellaneous),Electronic, Optical and Magnetic Materials

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