Abstract
An organic anion, 2-bromoethanesulfonate (BrC2H4SO3−), provides one bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and two bis(ethylenedithio)tetraselenafulvalene (BETS) salts, the compositions of which are β’’-β’’-(BEDT-TTF)2BrC2H4SO3 (1), β’’-β’’-(BETS)2BrC2H4SO3 (2), and θ-(BETS)2BrC2H4SO3 (3), respectively. Compound 1 shows a metal–insulator transition at around 70 K. Compound 2 is isomorphous to 1, and 3 is polymorphic with 2. Compounds 2 and 3 show metallic behavior at least down to 4.2 K. The pressure dependence of the electrical resistivity of 1 is also reported.
Funder
Japan Society for the Promotion of Science
Subject
Materials Chemistry,Chemistry (miscellaneous),Electronic, Optical and Magnetic Materials
Reference53 articles.
1. Electronic Properties of Organic Conductors;Mori,2016
2. Electrocrystallisation of conductive nonstoicheiometric adducts of tetrathiafulvalene with inorganic or organic anions, and of similar adducts of tetracyanoquinodimethane
3. Conducting Organic Radical Cation Salts with Organic and Organometallic Anions
4. Di(4,4′,5,5′-tetramethyl-∆2,2′-bi-1,3-diselenolyliden)ium trifluoromethanesulfonate, C21H24F3O3SSe8, (TMTSF)2CF3SO3;Soling;Acta Cryst.,1983
5. Crystal Structures of Complexes between Hexacyanobutadiene and Tetramethyltetrathiafulvalene and Tetramethylthiotetrathiafulvalene
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