Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields

Author:

Makulski Włodzimierz1ORCID,Słowiński Mateusz A.1ORCID,Garbacz Piotr1ORCID

Affiliation:

1. Laboratory of NMR Spectroscopy, Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland

Abstract

Nuclear magnetic resonance (NMR) is a branch of spectroscopy commonly used for identifying the chemical structure of various materials. One of the areas in which NMR provides accurate data is the determination of nuclear magnetic moments. This work reviews NMR experiments with the nuclei of light elements in simple molecules. Since nuclear shielding constants from up-to-date quantum calculations are now available, very accurate dipole moments of many nuclei can be determined. Recent experimental measurements of 1H, 2H, 3H, 3He, 6Li, 7Li, 9Be, 10B, and 11B nuclear magnetic moments and the appropriate theoretical predictions are presented and commented upon. Several achievements in this field using different methodologies, such as NMR spectroscopy, molecular beam experiments, and the Penning trap method are reported.

Publisher

MDPI AG

Subject

Materials Chemistry,Chemistry (miscellaneous),Electronic, Optical and Magnetic Materials

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