Oxidation–Responsive Emulsions Stabilized with Poly(Vinyl Pyrrolidone-co-allyl Phenyl Sulfide)

Abstract

Oxidation-responsive emulsions were obtained by stabilizing mineral oil droplets using amphiphilic poly(vinyl pyrrolidone-co-allyl phenyl sulfide) (P(VP-APS)). 1H nuclear magnetic resonance (NMR) spectroscopy revealed that P(VP-APS) whose APS content was 0%, 3.28%, 3.43% and 4.58% were successfully prepared by free radical reaction and the sulfide of APS was oxidized by H2O2 treatment. X-ray Photoelectron Spectroscopy (XPS) also disclosed that the sulfide of APS was oxidized to sulfone by the oxidizing agent. The optical density of copolymer solutions and the interfacial activity of the copolymers markedly decreased by H2O2 treatment possibly because the sulfide of APS was oxidized and the amphiphilicity of the copolymers were weakened. The increase rate of the oil droplet diameter of the emulsions was outstandingly promoted when H2O2 solution (10%, v/v) was used as an aqueous phase. The phase separation of the emulsions was also expedited by the oxidizing agent. The oxidation of APS and the weakened interfacial activity were thought to be a main reason for the demulsification of P(VP-APS)-stabilized emulsions.