The Impact of Aluminosilicate Additives upon the Chlorine Distribution and Melting Behavior of Poultry Litter Ash

Abstract

The use of poultry litter (PL) as a sustainable fuel is gaining more attention due to its wide availability and carbon neutrality. However, this type of feedstock is rich in ash and typically contains a high concentration of chlorine (Cl) and alkali elements (Na, K). Therefore, it is likely to cause unwanted issues during combustion and co-combustion, such as chlorine-induced corrosion, ash deposition, and bed agglomeration. In this study, for the first time, the influence of aluminosilicate additives on the above problems of poultry litter was investigated. Three aluminosilicate minerals are under consideration: kaolin, halloysite, and bentonite. Their influence on the chemical composition and meting tendencies of two poultry litter ashes are determined. The investigated ashes, PL1 and PL2, are characterized by different chlorine contents of 6.38% and 0.42%, respectively. The results show that in the case of the chlorine-rich PL1 ash, the additives reduced the chlorine content by up to 45%, resulting in a 3.93% of chlorine in the case of halloysite, 3.48% in the case of kaolin, and 4.25% in the case of bentonite. The additives also positively influenced the shrinkage starting temperature and the deformation temperature of the PL1 ash.