Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation

Author:

Vashchynskyi Vitalii1,Okhay Olena23ORCID,Boychuk Tetiana4

Affiliation:

1. The Department of General Physics, Lviv Polytechnic National University, 12 S. Bandery Str., 79013 Lviv, Ukraine

2. Centre for Mechanical Technology and Automation (TEMA), University of Aveiro, 3810-193 Aveiro, Portugal

3. LASI-Intelligent Systems Associate Laboratory, 4800-058 Guimaraes, Portugal

4. Institut de Ciència dels Materials (ICMUV), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain

Abstract

The aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation of narrow micropores and the carbon matrix. The adsorbent materials were characterized with FTIR and SEM, and a specific surface area was calculated. Moreover, additional activation by HNO3 and annealing at 450 °C led to an increase in surface area up to 1300 m2/g. The obtained N-enriched sorbents show adsorption activities of 190–235 mg/g for methylene blue and 210–260 mg/g for methyl orange. The results of this study can be useful for future scale-up using the apricot material as a low-cost adsorbent for the removal of dyes in environmental remediation production.

Funder

Ministry of Education and Science of Ukraine

FCT

Centro Portugal Regional Operational Programme

Publisher

MDPI AG

Subject

General Medicine

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