Combustion Synthesis of Chromium Nitrides

Abstract

This paper explores different modes of synthesis by combustion of chromium-nitrogen and ferrochromium-nitrogen alloys. The SH-synthesis of chromium nitrides and ferrochromium nitrides was performed. Regular patterns in layer-by-layer and surface modes of Cr combustion in nitrogen were investigated. The mechanism of non-stationary combustion during the synthesis of chromium was investigated. Regular patterns of chromium and ferrochromium combustion in the cocurrent filtration mode were analyzed, and the possibility to intensify the SHS process using the pressure filtration principle was assessed. The process of chromium powder combustion in the cocurrent flow of nitrogen-containing gas in the range of specific flow rates from 20 cm3/s·cm2 was investigated. Pressure filtration intensifies the process of combustion wave propagation in the Cr–N2 system. Here, the combustion rate increases while the degree of nitridation decreases. We discovered superadiabatic heating modes when the reaction zone was blown with pure nitrogen and a nitrogen-argon mixture. The tempering mode that was realized during pressure filtration allows for the uptake of high-temperature single-phase non-stoichiometric phases of Cr2N.