A Glance at a Sustainable Solution Using Vertical Constructed Wetland Based on Dewatered Drinking-Water Waste Augmented Nanoparticle Composite Substrate for Wastewater Treatment

Abstract

The current investigation introduces and demonstrates a credible, economically sound system to remove agrochemical runoff using a vertical flow constructed wetland (VFCW). DuPont 1179 carbamate insecticide was applied as a simulating greenhouse crop production controller, which resulted in runoff loaded with DuPont 1179. A novel composite of constructed wetland from an alum sludge conjugate magnetite nanoparticle substrate was applied and supported with gravel as a filtration/adsorption bed in a vertical flow constructed wetland (VFCW) system. X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM) augmented with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy (FTIR) were employed to characterize the suggested composite substrate. The experimental data showed VFCW to be significant in eliminating DuPont 1179. The isotherm time was explored at 300 min, which corresponded to complete insecticide removal (100%). The operational parameters were located at the natural pH (6.9) of the solution and room temperature (25 °C). The VFCW column was also investigated at various substrate concentrations ranging from 100% to 40% of the composite material supported by a gravel medium, and the existence of composite at a 75% concentration showed the highest yield. The experimental data verified that the adsorption followed the pseudo second-order adsorption kinetic model. Furthermore, according to the isotherm model results, the scheme followed the Langmuir isotherm model. Thus, the presented study is a promising indicator of the possibility of using alum sludge conjugate nanoparticles for the elimination of agrochemicals from wastewater.