Study of Thermal Effect on the Mechanical Properties of Nylon 610 Nanocomposites with Graphite Flakes That Have Undergone Supercritical Water Treatment at Different Temperatures

Abstract

This study investigates the thermal effect of supercritical water treatment at different temperatures (150, 175, 200 °C) and semi-vacuum state (−0.08 MPa) on graphite flakes which are then incorporated into nylon 610. The treatment is deemed to increase the surface activity of nanofillers through the formation of oxygen-containing functional groups. X-ray diffraction (XRD) analysis indicated that the crystal structure of the flakes remained similar before and after supercritical water treatment. Fourier transform infrared spectroscopy (FTIR) also showed the presence of hydrogen bonding between the flakes and the polymer matrix through the appearance of amide bands. The intensity of the amide peaks is higher for nanocomposites with treated flakes than untreated ones. Furthermore, scanning electron microscopy (SEM) showed that at higher wt%, aggregation will occur, which leads to a weakening in physical properties. The tensile strength of nanocomposites with treated flakes decreased with increasing wt%, while those with untreated flakes increased with increasing wt%. Young’s modulus of all the nanocomposites generally increased with increasing wt%. The highest tensile strength obtained is 967.02 kPa, while that of neat nylon 610 is 492.09 kPa. This enhancement in mechanical properties can be attributed to the intact structure of the graphite flakes and the interaction between the flakes and the nylon 610 matrix. A higher temperature of water treatment was discovered to cause higher oxidation levels on surface of the nanofillers but would result in some structural damage. The optimum nylon 610 nanocomposite synthesized was the one that was incorporated with 1.5 wt% graphite flakes treated at 150 °C and −0.08 MPa, as it has the highest tensile strength.