Developing an Effective and Durable Film for Marine Fouling Prevention from PDMS/SiO2 and PDMS/PU with SiO2 Composites

Abstract

Polymer film coating with a highly hydrophobic surface property is a practical approach to prevent fouling of any structures in the marine environment without affecting marine microorganisms. The preparation of a polymer coating, from a simple and easy method of solution blending of hydrophobic polydimethylsiloxane elastomer and hydrophilic polyurethane with SiO2, was carried out in this study, with the aim of improving characteristics, and the coating demonstrated economic feasibility for antifouling application. Incorporation of SiO2 particles into PDMS and PDMS/PU polymer film improved mechanical properties of the film and the support fabrication of micropatterns by means of a soft lithography process. Observations from field emission scanning electron microscope (FESEM) of the PDMS/SiO2 composite film revealed a homogeneous morphology and even dispersion of the SiO2 disperse phase between 1–5 wt.%. Moreover, the PDMS film with 3 wt.% loading of SiO2 considerably increased WCA to 115.7° ± 2.5° and improved mechanical properties by increasing Young’s modulus by 128%, compared with neat PDMS film. Additionally, bonding strength between barnacles and the PDMS film with 3 wt.% of SiO2 loading was 0.16 MPa, which was much lower than the bonding strength between barnacles and the reference carbon steel of 1.16 MPa. When compared to the previous study using PDMS/PU blend (95:5), the count of barnacles of PDMS with 3 wt.% SiO2 loading was lower by 77% in the two-week field tests and up to 97% in the eight-week field tests. Subsequently, when PDMS with 3 wt.% SiO2 was further blended with PU, and the surface modified by the soft lithography process, it was found that PDMS/PU (95:5) with 3 wt.% SiO2 composite film with micropatterns increased WCA to 122.1° ± 2.9° and OCA 90.8 ± 3.6°, suggesting that the PDMS/PU (95:5) with 3 wt.% SiO2 composite film with surface modified by the soft lithography process could be employed for antifouling application.