Ultrafast Pump–Probe Spectroscopy in Organic Dirac Electron Candidate α-(BETS)2I3

Author:

Tsuchiya Satoshi1ORCID,Katsumi Masato1,Oka Ryuhei2,Naito Toshio2ORCID,Toda Yasunori1

Affiliation:

1. Department of Applied Physics, Hokkaido University, Sapporo 060-8628, Hokkaido, Japan

2. Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Ehime, Japan

Abstract

Photo-induced carrier dynamics were measured in the organic Dirac electron candidate α-(BETS)2I3 to investigate why resistivity increases below TMI = 50 K. We found a change in carrier dynamics due to an insulating gap formation below T′ = 50 K. On the other hand, the relaxation time and polarization anisotropy of the observed dynamics differ from those in the charge-ordering (CO) state of the isostructural salt α-(ET)2I3. Based on the difference, it can be concluded that the insulating phase has a different origin than the CO state.

Funder

JSPS KAKENHI

Publisher

MDPI AG

Subject

Condensed Matter Physics,Electronic, Optical and Magnetic Materials

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