Enhancing the Storage Stability and Rutting Resistance of Modified Asphalt through Surface Functionalization of Waste Tire Rubber Powder

Abstract

Waste tire rubber powder-modified asphalt (RMA) has been widely used in road construction, which was traditionally limited by the poor compatibility of RMA, affecting pavement performance. By synthesizing epoxy soybean oil with amide groups (ESO/TETA) and grafting it onto desulfurized rubber powder (DCR) through microwave irradiation, a surface-functionalized rubber powder (MDCR) was produced successfully. The effects of the physical properties, storage stability, thermal stability, and rheological behavior of the modified asphalt were studied. The results show that the MDCR with a polar surface improved the compatibility and adhesive interactions between the modified crumb rubber and the asphalt. The MDCR content could reach 50%, and the phase separation could meet the requirements of 2.2 °C, which has application conditions in engineering for stable storage. Additionally, the inclusion of MDCR in the asphalt formulations significantly mitigated the temperature sensitivity of the modified asphalt. Importantly, when the MDCR constituted from 20% to 50% of the asphalt, there was a noted reduction in the phase angle at temperatures above 70 °C, indicating a significant improvement in the elastic efficiency. The MDCR also led to substantial enhancements in the resistance of the asphalt to high-temperature and high-stress rutting, addressing the crucial limitations in the consumption ability of waste tire rubber powder and improving the overall performance of RMA in pavement applications.