Phosphate Surface Treatment for Improving the Corrosion Resistance of the C45 Carbon Steel Used in Carabiners Manufacturing

Abstract

This study approaches the issues which appear during carabiner use and analyses the possibility to eliminate them. Therefore, to improve the corrosion resistance of carbon steel, used in carabiners manufacturing, three different insoluble phosphate layers were deposited on the samples’ surface. The layers were obtained by immersion in zinc-based phosphate solution, zinc/iron-based phosphate solution and manganese-based phosphate solution, Afterwards, to protect against mechanical shocks, a layer of elastomer-based paint was deposited. Furthermore, to reduce rope wear by decreasing the value of the coefficient of friction, the samples were impregnated in molybdenum disulfide-based lubricant. This study aims to analyse the corrosion behaviour of the layers deposited on the carbon steel surface in three of the most common corrosive environments (rainwater, seawater and fire extinguishing solution) by linear and cyclic polarisation. The overall results show that all types of deposited layers increase the corrosion resistance of C45 steel. The experimental results revealed that the samples coated with a phosphate layer obtained by immersion in the zinc-based phosphate solution possess the highest corrosion resistance among the phosphate samples.