Preparation of Gradient Materials with Molten Salts Electrodeposition

Abstract

A new way of preparing W–Cu functional gradient materials (FGM) with molten salts electrodeposition is studied. The results show that, with the conditions of current density 70 mA·cm−2, electrodeposition temperature 700 °C and bidirectional pulse electrodepositing for 30 minutes (min), the Cu–Ni gradient layer prepared under this condition is widely used dense and smooth. Fundamental to the preparation of Cu–Ni functional gradient layer, Cu–Ni is used as a cathode to deposit W. Under the current density of 50 mA·cm−2, the time of 20 min, with bidirectional pulse electrodeposition, the Cu+Ni+W gradient layer has uniform composition gradient change and larger thickness. The W–Cu gradient materials prepared in this study have good cohesiveness. The addition of Ni would promote the inter-diffusion of Cu and W, and increase the diffusion coefficient significantly.