Dispersion Homogeneity of Silicon Anode Slurries with Various Binders for Li-Ion Battery Anode Coating

Abstract

We aimed to determine the relationship between surface chemistry and the rheological properties of silicon anode slurries in lithium-ion batteries. To accomplish this, we investigated the use of various binders such as PAA, CMC/SBR, and chitosan as a means to control particle aggregation and improve the flowability and homogeneity of the slurry. Additionally, we utilized zeta potential analysis to examine the electrostatic stability of the silicon particles in the presence of different binders, and the results indicated that the conformations of the binders on the silicon particles can be influenced by both neutralization and the pH conditions. Furthermore, we found that the zeta potential values served as a useful metric for evaluating binder adsorption and particle dispersion in the solution. We also conducted three-interval thixotropic tests (3ITTs) to examine the structural deformation and recovery characteristics of the slurry, and the results demonstrated that these properties vary depending on the strain intervals, pH conditions, and chosen binder. Overall, this study emphasized the importance of taking into account surface chemistry, neutralization, and pH conditions when assessing the rheological properties of the slurry and coating quality for lithium-ion batteries.