Study of the Mechanical Properties and Microstructure of Alkali-Activated Fly Ash–Slag Composite Cementitious Materials

Abstract

Composites that use fly ash and slag as alkali-activated materials instead of cement can overcome the defects and negative effects of alkali-activated cementitious materials prepared with the use of an alkali-activated material. In this study, fly ash and slag were used as raw materials to prepare alkali-activated composite cementitious materials. Experimental studies were carried out on the effects of the slag content, activator concentration and curing age on the compressive strength of the composite cementitious materials. The microstructure was characterized using hydration heat, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM), and its intrinsic influence mechanism was revealed. The results show that increasing the curing age improves the degree of polymerization reaction and the composite reaches 77~86% of its 7-day compressive strength after 3 days. Except for the composites with 10% and 30% slag content, which reach 33% and 64%, respectively, of their 28-day compressive strength at 7 days, the remaining composites reach more than 95%. This result indicates that the alkali-activated fly ash–slag composite cementitious material has a rapid hydration reaction in the early stage and a slow hydration reaction in the later stage. The amount of slag is the main influencing factor of the compressive strength of alkali-activated cementitious materials. The compressive strength shows a trend of continuous increase when increasing slag content from 10% to 90%, and the maximum compressive strength reaches 80.26 MPa. The increase in the slag content introduces more Ca2+ into the system, which increases the hydration reaction rate, promotes the formation of more hydration products, refines the pore size distribution of the structure, reduces the porosity, and forms a denser microstructure. Therefore, it improves the mechanical properties of the cementitious material. The compressive strength shows a trend of first increasing and then decreasing when the activator concentration increases from 0.20 to 0.40, and the maximum compressive strength is 61.68 MPa (obtained at 0.30). The increase in the activator concentration improves the alkaline environment of the solution, optimizes the level of the hydration reaction, promotes the formation of more hydration products, and makes the microstructure denser. However, an activator concentration that is too large or too small hinders the hydration reaction and affects the strength development of the cementitious material.