Comparison of Solidification Characteristics between Polymer-Cured and Bio-Cured Fly Ash in the Laboratory

Abstract

Fly ash (FA) usually causes air and soil pollution due to wind erosion. However, most FA field surface stabilization technologies have long construction periods, poor curing effects, and secondary pollution. Therefore, there is an urgent need to develop an efficient and environmentally friendly curing technology. Polyacrylamide (PAM) is an environmental macromolecular chemical material for soil improvement, and Enzyme Induced Carbonate Precipitation (EICP) is a new friendly bio-reinforced soil technology. This study attempted to use chemical, biological, and chemical-biological composite treatment solutions to solidify FA, and the curing effect was evaluated by testing indicators, such as unconfined compressive strength (UCS), wind erosion rate (WER), and agglomerate particle size. The results showed that due to the viscosity increase in the treatment solution, with the increase in PAM concentration, the UCS of the cured samples increased first (from 41.3 kPa to 376.1 kPa) and then decreased slightly (from 376.1 kPa to 367.3 kPa), while the wind erosion rate of the cured samples decreased first (from 39.567 mg/(m2·min) to 3.014 mg/(m2·min)) and then increased slightly (from 3.014 mg/(m2·min) to 3.427 mg/(m2·min)). Scanning electron microscopy (SEM) indicated that the network structure formed by PAM between the FA particles improved the physical structure of the sample. On the other hand, PAM increased the nucleation sites for EICP. Due to the stable and dense spatial structure formed by the “bridging” effect of PAM and the cementation of CaCO3 crystals, the mechanical strength, wind erosion resistance, water stability, and frost resistance of the samples cured by PAM-EICP were increased significantly. The research will provide curing application experience and a theoretical basis for FA in wind erosion areas.