Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process

Author:

Luciano Giorgio1ORCID,Vignolo Maurizio1,Brunengo Elisabetta1,Utzeri Roberto1,Stagnaro Paola1ORCID

Affiliation:

1. Istituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, Italy

Abstract

The present paper reports on the formulation and characterization of composite coating materials susceptible to microwave (MW) heating to investigate their application in making the rotomolding process (RM) more energy efficient. SiC, Fe2SiO4, Fe2O3, TiO2 and BaTiO3 and a methyl phenyl silicone resin (MPS) were employed for their formulations. Experimental results showed that the coatings with a ratio of 2:1 w/w of inorganic/MPS are the most MW-susceptible materials. To test the coatings in working mimicking conditions, they were applied to molds, and polyethylene samples were manufactured by MW-assisted laboratory uni-axial RM and then characterized by calorimetry, infrared spectroscopy and tensile tests. The results obtained suggest that the coatings developed can be successfully applied to convert molds employed for classical RM process to MW-assisted RM processes.

Funder

Italian Ministry of Economic Development

Liguria Region and Lombardy Region

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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