Development and Characterization of a Sustainable Bio-Polymer Concrete with a Low Carbon Footprint

Author:

Murcia Daniel Heras1ORCID,Al Shanti Siham1ORCID,Hamidi Fatemeh1ORCID,Rimsza Jessica2,Yoon Hongkyu2,Gunawan Budi2ORCID,Abdellatef Mohammed2,Taha Mahmoud Reda1ORCID

Affiliation:

1. Department of Civil, Construction & Environmental Engineering, University of New Mexico, Albuquerque, NM 87131, USA

2. Sandia National Laboratories, MS 0748, 1515 Eubank Blvd. SE, Albuquerque, NM 87123, USA

Abstract

Polymer concrete (PC) has been used to replace cement concrete when harsh service conditions exist. Polymers have a high carbon footprint when considering their life cycle analysis, and with increased climate change concerns and the need to reduce greenhouse gas emission, bio-based polymers could be used as a sustainable alternative binder to produce PC. This paper examines the development and characterization of a novel bio-polymer concrete (BPC) using bio-based polyurethane used as the binder in lieu of cement, modified with benzoic acid and carboxyl-functionalized multi-walled carbon nanotubes (MWCNTs). The mechanical performance, durability, microstructure, and chemical properties of BPC are investigated. Moreover, the effect of the addition of benzoic acid and MWCNTs on the properties of BPC is studied. The new BPC shows relatively low density, appreciable compressive strength between 20–30 MPa, good tensile strength of 4 MPa, and excellent durability resistance against aggressive environments. The new BPC has a low carbon footprint, 50% lower than ordinary Portland cement concrete, and can provide a sustainable concrete alternative in infrastructural applications.

Funder

Sandia National Laboratories

U.S. Department of Energy’s National Nuclear Security Administration

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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