Solution-Processable NiOx:PMMA Hole Transport Layer for Efficient and Stable Inverted Organic Solar Cells

Author:

Kong Tianyu1ORCID,Yang Genjie1ORCID,Fan Pu1,Yu Junsheng1ORCID

Affiliation:

1. State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 610054, China

Abstract

For organic solar cells (OSCs), nickel oxide (NiOx) is a potential candidate as the hole transport layer (HTL) material. However, due to the interfacial wettability mismatch, developing solution-based fabrication methods of the NiOx HTL is challenging for OSCs with inverted device structures. In this work, by using N, N-dimethylformamide (DMF) to dissolve poly(methyl methacrylate) (PMMA), the polymer is successfully incorporated into the NiOx nanoparticle (NP) dispersions to modify the solution-processable HTL of the inverted OSCs. Benefiting from the improvements of electrical and surface properties, the inverted PM6:Y6 OSCs based on the PMMA-doped NiOx NP HTL achieves an enhanced power conversion efficiency of 15.11% as well as improved performance stability in ambient conditions. The results demonstrated a viable approach to realize efficient and stable inverted OSCs by tuning the solution-processable HTL.

Funder

National Science Foundation of China

Sichuan Science and Technology Program

Sichuan Province Key Laboratory of Display Science and Technology

Qiantang Science and Technology Innovation Center

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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