Bilayer Films of Poly(lactic acid) and Cottonseed Protein for Packaging Applications

Author:

Biswas Atanu1ORCID,Cheng Huai N.2ORCID,Kuzniar Gary1,He Zhongqi2ORCID,Kim Sanghoon1ORCID,Furtado Roselayne F.3ORCID,Alves Carlucio R.4ORCID,Sharma Brajendra K.5ORCID

Affiliation:

1. National Center for Agricultural Utilization Research, USDA Agricultural Research Service, Peoria, IL 61604, USA

2. Southern Regional Research Center, USDA Agricultural Research Service, New Orleans, LA 70124, USA

3. Embrapa Agroindústria Tropical, Rua Dra. Sara Mesquita 2270, Fortaleza 60511-110, CE, Brazil

4. Chemistry Department, State University of Ceará, Silas Munguba Av. 1.700, Fortaleza 60740-020, CE, Brazil

5. Eastern Regional Research Center, USDA Agricultural Research Service, Wyndmoor, PA 19038, USA

Abstract

Poly(lactic acid) (PLA) is a common biobased film-former made from renewable biomass, such as polysaccharides from sugarcane, corn, or cassava. It has good physical properties but is relatively expensive when compared to the plastics used for food packaging. In this work, bilayer films were designed, incorporating a PLA layer and a layer of washed cottonseed meal (CSM), an inexpensive agro-based raw material from cotton manufacturing, where the main component is cottonseed protein. These bilayer films were made through the solvent casting method. The combined thickness of the PLA/CSM bilayer film was between 47 and 83 μm. The thickness of the PLA layer in this film was 10%, 30%, or 50% of the total bilayer film’s thickness. Mechanical properties of the films, opacity, water vapor permeation, and thermal properties were evaluated. Since PLA and CSM are both agro-based, sustainable, and biodegradable, the bilayer film may be used as an eco-friendlier food packaging material, which helps reduce the environmental problems of plastic waste and microplastics. Moreover, the utilization of cottonseed meal may add value to this cotton byproduct and provide a potential economic benefit to cotton farmers.

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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