CVD Deposited Epoxy Copolymers as Protective Coatings for Optical Surfaces

Author:

Karabıyık Merve1ORCID,Cihanoğlu Gizem1ORCID,Ebil Özgenç1ORCID

Affiliation:

1. Department of Chemical Engineering, İzmir Institute of Technology, 35430 Urla, Turkey

Abstract

Copolymer thin films of glycidyl methacrylate (GMA), ethylene glycol dimethacrylate (EGDMA) and 2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane (V4D4) were synthesized via initiated chemical vapor deposition (iCVD) as protective coatings for optical surfaces. Chemical durability in various solvents, corrosion resistance, adhesion to substrate, thermal resistance and optical transmittance of the films were evaluated. Crosslinked thin films exhibited high chemical resistance to strong organic solvents and excellent adhesion to substrates. Poly(GMA-co-EGDMA) and poly(GMA-co-V4D4) copolymers demonstrated protection against water (<1% thickness loss), high salt resistance (<1.5% thickness loss), and high optical transparency (~90% in visible spectrum) making them ideal coating materials for optical surfaces. Combining increased mechanical properties of GMA and chemical durability V4D4, the iCVD process provides a fast and low-cost alternative for the fabrication of protective coatings.

Funder

Izmir Institute of Technology

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

Reference70 articles.

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