Polypropylene Degradation on Co-Rotating Twin-Screw Extruders

Author:

Altepeter Matthias1ORCID,Schöppner Volker1,Wanke Sven1,Austermeier Laura1,Meinheit Philipp1,Schmidt Leon1

Affiliation:

1. Kunststofftechnik Paderborn, Paderborn University, 33098 Paderborn, Germany

Abstract

Nowadays, usable plastic materials with defined properties are created by blending additives into the base polymer. This is the main task of compounding on co-rotating twin-screw extruders. The thermal and mechanical stress occurring in the process leads to a mostly irreversible damage to the material. Consequently, the properties of the polymer melt and the subsequent product are affected. The material degradation of polypropylene (PP) on a 28 mm twin-screw extruder has already been studied and modeled at Kunststofftechnik Paderborn. In this work, the transferability of the previous results to other machine sizes and polypropylene compounds were investigated experimentally. Therefore, pure polypropylene was processed with screw diameters of 25 mm and 45 mm. Furthermore, polypropylene compounds with titanium dioxide as well as carbon fibers were considered on a 28 mm extruder. In the course of the evaluation of the pure polypropylene, the melt flow rates of the samples were measured and the molar masses were calculated on this basis. The compounds were analyzed by gel permeation chromatography. As in the previous investigations, high rotational speeds, low throughputs and high melt temperatures lead to a higher material degradation. In addition, it is illustrated that the previously developed model for the calculation of material degradation is generally able to predict the degradation even for different machine sizes by adjusting the process coefficients. In summary, this article shows that compounders can use the recommendations for action and the calculation model for the material degradation of polypropylene, irrespective of the machine size, to design processes that are gentle on the material.

Funder

Deutsche Forschungsgemeinschaft

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. A comprehensive review on residence time distributions in co-rotating twin-screw extrusion;International Polymer Processing;2024-08-19

2. Visualization of Polymer Chain Scission during Melt Processing Using a Mechanochromic Probe;Macromolecules;2024-07-18

3. Design of Expert PID-based Temperature Control System for Extrusion Machine;2023 International Annual Conference on Complex Systems and Intelligent Science (CSIS-IAC);2023-10-20

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