Epoxy Resins for Flooring Applications, an Optimal Host for Recycling Deactivated Cement Asbestos

Author:

Campanale Fabrizio1ORCID,Vergani Fabrizio1,Marian Narcisa Mihaela2ORCID,Viti Cecilia2,Bianchi Alberto3,Ferrario Silvia3,Mauri Michele4ORCID,Capitani Giancarlo1ORCID

Affiliation:

1. Department of Earth and Environmental Sciences (DISAT), University of Milano-Bicocca, Piazza della Scienza 4, 20126 Milano, Italy

2. Department of Physical Science, Earth, and Environment (DSFTA), University of Siena, Via Laterina 8, 53100 Siena, Italy

3. Graftonica Srl, Via Martiri Triestini 7, 20148 Milan, Italy

4. Department of Materials Science, University of Milano-Bicocca, Via Roberto Cozzi 55, 20125 Milan, Italy

Abstract

Cement asbestos slates, commonly known as Eternit® and still abundant in private and public buildings, were deactivated through a thermal process. The resulting deactivated cement asbestos powder (DCAP), a mixture of Ca-Mg-Al silicates and glass, was compounded with Pavatekno Gold 200 (PT) and Pavafloor H200/E (PF), two different epoxy resins (bisphenol A epichlorohydrin) for flooring applications. The addition of the DCAP filler to the PF samples causes a slight but acceptable decrease in the relevant mechanical properties (compressive, tensile, and flexural strengths) upon increasing DCAP content. The addition of the DCAP filler to pure epoxy (PT resin) causes a slight decrease in the tensile and flexural strengths with increasing DCAP content, while the compressive strength is almost unaffected, and the Shore hardness increases. The main mechanical properties of the PT samples are significantly better than those of the filler-bearing sample of normal production. Overall, these results suggest that DCAP can be advantageously used as filler in addition to, or in substitution for, commercial barite. In particular, the sample with 20 wt% of DCAP is the best performing in terms of compressive, tensile, and flexural strengths, whereas the sample with 30 wt% of DCAP shows the highest Shore hardness, which is an important property to be considered in flooring applications.

Funder

Italian Ministero per la Transizione Ecologica

A-FIRE

Fondazione Cariplo

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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