Microstructural and Mechanical Properties of Alkali Activated Materials from Two Types of Blast Furnace Slags

Abstract

This paper investigated the effect of blast furnace slags (BFS) characteristics on the properties achievement after being alkali activated. The physical and chemical characteristics of BFS were determined by X-ray fluorescence (XRF), X-ray Diffraction (XRD) and laser granulometry. Multi-technical characterizations using calorimetry, XRD, Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetry (TG-DTG), scanning electron microscope (SEM), nitrogen sorption and uniaxial compressive strength (UCS) were applied to give an in-depth understanding of the relationship between the reaction products, microstructure and BFS characteristics. The test results show that the microstructure and mechanical properties of alkali activated blast furnace slags (BFS) highly depend on the characteristics of BFS. Although the higher content of basic oxide could accelerate the hydration process and result in higher mechanical properties, a poor thermal stabilization was observed. On the other hand, with a higher content of Fe, the hydration process in alkali activated BFS2 lasts for a longer time, contributing to a delayed compressive strength achievement.