Au Doping PtNi Nanodendrites for Enhanced Electrocatalytic Methanol Oxidation Reaction

Author:

Wang Shan1,Ma Lifeng1,Song Dan1,Yang Shengchun234

Affiliation:

1. Key Laboratory for Molecular Genetic Mechanisms and Intervention Research on High Altitude Disease of Tibet Autonomous Region, School of Medicine, Xizang Minzu University, No. 6 East Wenhui Road, Xianyang 712082, China

2. Ministry of Education Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Key Laboratory of Shaanxi for Advanced Materials and Mesoscopic Physics, State Key Laboratory for Mechanical Behavior of Materials, School of Physics, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China

3. National Innovation Platform (Center) for Industry-Education Integration of Energy Storage Technology, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China

4. Shaanxi Collaborative Innovation Center for Hydrogen Fuel Cell Performance Improvement, Xi’an Jiaotong University, No. 28 West Xianning Road, Xi’an 710049, China

Abstract

To boost the electrocatalytic methanol oxidation reaction (MOR) of Platinum (Pt), making binary PtM (M = transition metals, for example, Fe, Cu, and Ni) with specific morphology is known as a promising method. Although great progress has been made in the synthesis of shaped PtM catalysts toward MOR, enhancing the catalytic performance of the PtM to enable it to be commercialized is still a hotspot. In this work, the Au-doped PtNi dendritic nanoparticles (Au-PtNi DNPs) were obtained by doping a small amount of gold (Au) into initially prepared PtNi DNPs, greatly improving their MOR catalytic activity and durability. The energy-dispersive X-ray spectroscopy mapping (EDXS) indicates that the surface of DNPs is mainly composed of Au dopant and PtNi, while the core is mainly Pt, indicating the formation of Au-doped PtNi/Pt core-shell-like DNP structures. The electrocatalytic performance of the prepared Au-PtNi DNPs with different compositions for the MOR was evaluated using cyclic voltammetry, chronoamperometry, and CO-stripping tests. The experimental findings indicate that the Au-PtNi DNPs showed better MOR performance in comparison with PtNi DNPs and commercial Pt catalysts. Among all the catalysts, 6% Au-PtNi DNPs showed 4.3 times improved mass catalytic activity for the MOR in comparison with commercial Pt catalysts. In addition, all the prepared Au-PtNi DNPs display a remarkable CO tolerance compared to that of PtNi DNPs and commercial Pt catalysts. The dendritic structure of Au-PtNi DNPs can effectively enhance catalytic performance, combined with the electronic effect of Au, Pt, and Ni.

Funder

Natural Science Foundation of Xizang Autonomous Region

Natural Science Project of the Education Department of Shaanxi Provincial Government

Scientific Research Project of Xizang Minzu University

Research Fund for Advanced Talents of Xizang Minzu University

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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