Detection of Dimethyl Methyl Phosphonate by Silica Molecularly Imprinted Materials

Author:

Wang Xuming1,Li Xin1ORCID,Wu Qiang1,Yuan Yubin1,Liu Weihua1ORCID,Han Chuanyu1,Wang Xiaoli2

Affiliation:

1. Department of Microelectronics, Xi’an Jiaotong University, Xi’an 710049, China

2. School of Physics, Xi’an Jiaotong University, Xi’an 710049, China

Abstract

In recent years, the increasing severity of chemical warfare agent threats to public safety has led to a growing demand for gas sensors capable of detecting these compounds. However, gas sensors used for the detection of chemical warfare agents must overcome limitations in sensitivity, selectivity, and reaction speed. This paper presents a sensitive material and a surface acoustic gas sensor for detecting dimethyl methyl phosphonate. The results demonstrate that the sensor exhibits good selectivity and could detect 80 ppb of dimethyl methyl phosphonate within 1 min. As an integral component of the sensor, the microstructure and adsorption mechanism of silica molecular imprinting material were studied in detail. The results show that the template molecule could significantly affect the pore volume, specific surface area, and hydroxyl density of mesoporous materials. These properties further affect the performance of the sensor. This study provides a valuable case study for the design of sensitive materials.

Funder

National Natural Science Foundation of China

National Defense Project

Fundamental Research Funds for the Central Universities

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

Reference38 articles.

1. Acetylcholinesterase inhibitors: Phar-macology and toxicology;Curr. Neuropharmacol.,2013

2. MEMS-based gas chromatography column for the analysis of chemical warfare agent(CWA) simulates;Li;Appl. Mech. Mater.,2014

3. Gas chromatography-full scan mass spectrometry determina-tion of traces of chemical warfare agents and their impurities in air samples by inlet based thermal desorption of sorbent tubes;Terzic;J. Chromatogr. A,2012

4. Phillips, C.M., and Tan, H.W. (2010). Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XI, SPIE.

5. A review of recent, unconventional applications of ion mobility spectrometry (IMS);Armenta;Anal. Chim. Acta,2011

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3