Heterogeneous Catalysis in (Bio)Ethanol Conversion to Chemicals and Fuels: Thermodynamics, Catalysis, Reaction Paths, Mechanisms and Product Selectivities

Author:

Garbarino Gabriella,Pampararo Giovanni,Phung Thanh KhoaORCID,Riani PaolaORCID,Busca GuidoORCID

Abstract

In gas/solid conditions, different chemicals, such as diethylether, ethylene, butadiene, higher hydrocarbons, acetaldehyde, acetone and hydrogen, can be produced from ethanol with heterogeneous catalytic processes. The focus of this paper is the interplay of different reaction paths, which depend on thermodynamic factors as well as on kinetic factors, thus mainly from catalyst functionalities and reaction temperatures. Strategies for selectivity improvements in heterogeneously catalyzed processes converting (bio)ethanol into renewable chemicals and biofuels are also considered.

Publisher

MDPI AG

Subject

Energy (miscellaneous),Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electrical and Electronic Engineering,Control and Optimization,Engineering (miscellaneous)

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