Screening of Low-Dosage Methanol as a Hydrate Promoter

Abstract

We report a quantitative study of the effect of low-concentration methanol (MeOH) on the formation and dissociation of hydrates based on CH4 and CO2/N2 guest molecules. The kinetic promotion and dissociation ability of MeOH is also compared with the anionic surfactant sodium dodecyl sulfate (SDS, 100 ppm, 50 ppm). The effects of concentration changes (1 wt% and 5 wt%), pressure (p = 80–120 bar), guest molecules (CH4 and CO2), and temperature (1 °C and below 0 °C) are investigated using slow constant ramp (SCR) and isothermal (IT) temperature schemes. The results show that the kinetics are affected by the guest molecule and MeOH concentration. For CH4 gas, 5 wt% MeOH shows better promotion, while for CO2/N2 gas mixtures, 1 wt% MeOH gives better promotion. This conclusion agrees well with our previous results demonstrating optimal CH4 recovery and CO2 storage in the presence of 5 wt% MeOH. The promoting and inhibiting properties of MeOH could be beneficial in CH4 production from gas hydrate using CO2-rich gas injection, as delayed hydrate film formation in the presence of MeOH could improve both CH4 recovery and CO2 storage.