Characterization of Breakdown Arcs Induced by Venting Particles Generated by Thermal Runaway of Large-Capacity Ternary Lithium-Ion Batteries

Abstract

In recent years, with the continuous growth in power demand, lithium-ion batteries (LIBs) have become an indispensable component of various electronic devices, transportation vehicles, and energy systems. The safety performance of LIBs is one of the most significant issues facing their continued development. In battery systems, the presence of arcs constitutes a significant safety hazard that necessitates attention; the thermal runaway (TR) of LIBs releases a large quantity of particles with elevated temperature and high velocity, probably resulting in arc failures. Changes in the insulation structure inside battery packs and the accumulation of particulate matter resulting from the TR of battery cells are potential causes of arc-induced disasters. In this study, we utilized fully charged 71 Ah ternary LIB Li (Ni0.8Co0.1Mn0.1) O2 (NCM811) pouch cell samples and collected the vented particles in an inert atmosphere after TR. All the settled particles were classified into six groups; by conducting experiments with different particle sizes, electrode spacings, and circuit loads, the patterns of the particle-induced arcs were understood. The results indicate that as the particle size increases, the critical breakdown voltage decreases. Regarding electrode spacing and circuit load resistance, larger values require higher critical breakdown voltages. The research results provide valuable guidance for the electrical protection and safety design of battery systems.