Study on Co-Estimation of SoC and SoH for Second-Use Lithium-Ion Power Batteries

Abstract

Lithium-ion batteries are an ideal power supplier for electric vehicles (EVs) due to their high-power density and wide operating voltage, but their performance decays to 80% before retirement from EVs. Nevertheless, they still have a particular use value after decommissioning, so recycling the retired power battery in cascade can be considered. Therefore, accurate estimation of battery state-of-charge (SoC) and state-of-health (SoH) is crucial for extending the service life and echelon utilization of power lithium-ion battery packs. This paper proposes a comprehensive co-estimation scheme of battery SoC/SoH for the second-use of lithium-ion power batteries in EVs under different cycles using an adaptive extended Kalman filter (AEKF). First, according to the collected battery test data at different aging cycle levels, the external battery characteristics are analyzed, and then a cycle-dependent equivalent circuit model (cECM) is built up. Next, the parameter estimation of this battery model is performed via a recursive least square (RLS) algorithm. Meanwhile, the variations in internal battery parameters of the cycle numbers are fitted and synthesized. Moreover, validation of the estimated parameters is further carried out. Based on this enhanced battery model, the AEKF algorithm is utilized to fulfill battery SoC/SoH estimation simultaneously. The estimated results of SoC/SoH are obtained for a LiCoO2 cell in the case of CCC (constant current condition) under different cycle times. The results show that this proposed co-estimation scheme can predict battery SoC and SoH well, wherein the peak values of the SoC errors are less than 2.2%, and the peak values of SoH, calculated by the estimated capacity and internal resistance, are less than 1.7% and 2.2%, respectively. Hence, this has important guiding significance for realizing the cascade utilization of lithium-ion power batteries.