Thermodynamic Functions of a Metal Exposed to High Energy Densities in Compressed and Expanded States

Abstract

The development of a wide-range phenomenological model of metal with a small number of adjustable parameters for studying the behavior of metals in expanded and compressed states under the exposition of high energy density fluxes is the objective of the paper present. Both the reference data, methods of the quantum-statistical model of the atom, the density functional theory, and the requirement to the expanded and compressed states description of metal should be consistent on their boundary were used in the model. The expressions for thermodynamic functions and the critical parameters of expanded iron were obtained within the framework of the soft sphere model. The Grüneisen parameters calculated for the expanded and compressed states of the metal appear to be in good agreement with each other was shown. A calculation technique of the ion component average charge of the metal in expanded and compressed states is proposed. The experimentally defined volume range of V/V0 = 3–4 in which the character of iron conductivity changes from metallic to non-metallic includes the obtained in frameworks of our approach value of the critical volume: V/V0 = 3.802 was established. The behavior of the average charge of the ion component is discussed. The contribution of the thermal electrons to the thermodynamic functions is evaluated.