Abstract
Advanced oxidation processes (AOPs) have become a favored approach in wastewater treatment due to the high efficiency and diverse catalyzed ways. Iron-based materials were the commonly used catalyst due to their environmental friendliness and sustainability in the environment. We collected the published papers relative to the application of the modified iron-based materials in AOPs between 1999 and 2020 to comprehensively understand the related mechanism of modified materials to improve the catalytic performance of iron-based materials in AOPs. Related data of iron-based materials, modification types, target pollutants, final removal efficiencies, and rate constants were extracted to reveal the critical process of improving the catalytic efficiency of iron-based materials in AOPs. Our results indicated that the modified materials through various mechanisms to enhance the catalytic performance of iron-based materials. The principal aim of iron-based materials modification in AOPs is to increase the content of available Fe2+ and enhance the stability of Fe2+ in the system. The available Fe2+ is elevated by the following mechanisms: (1) modified materials accelerate the electron transfer to promote the Fe3+/Fe2+ reaction cycle in the system; (2) modified materials form chelates with iron ions and bond with iron ions to avoid Fe3+ precipitation. We further analyzed the effect of different modifying materials in improving these two mechanisms. Combining the advantages of different modified materials to develop iron-based materials with composite modification methods can enhance the catalytic performance of iron-based materials in AOPs for further application in wastewater treatment.
Funder
National Natural Science Foundation of China
China Postdoctoral Science Foundation
Science and Technology Commission of Shanghai Municipality
Subject
Water Science and Technology,Aquatic Science,Geography, Planning and Development,Biochemistry
Cited by
3 articles.
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