New Approaches to the Synthesis and Stabilization of Polymer Microspheres with a Narrow Size Distribution

Author:

Gritskova Inessa A.1,Prokopov Nikolay I.1ORCID,Ezhova Anna A.1,Chalykh Anatoly E.2ORCID,Gusev Sergey A.34,Levachev Sergey M.5,Zubov Vitaly P.1,Gomzyak Vitaly I.16ORCID,Skopintsev Ivan V.34,Stuzhuk Alexander N.1,Kovtun Ivan D.1,Shulgin Anton M.1,Ivashkevich Dmitry S.1ORCID,Romanenko German A.1,Lakhtin Valentin G.7,Chvalun Sergei N.16ORCID

Affiliation:

1. Department of Chemistry and Technology of Macromolecular Compounds, MIREA—Russian Technological University (RTU MIREA), 119454 Moscow, Russia

2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IPCE RAS), Leninskiy Prospekt 31, 119071 Moscow, Russia

3. Federal Research and Clinical Center of Physical-Chemical Medicine of Federal Medical Biological Agency, Malaya Pirogovskaya 1a, 119435 Moscow, Russia

4. Federal State Autonomous Educational Institution of Higher Education “Pirogov Russian National Research Medical University”, Ministry of Health of the Russian Federation, Ostrovitjanova St. 1, 117997 Moscow, Russia

5. Faculty of Chemistry, Lomonosov Moscow State University, GSP-1, 1-3 Leninskiye Gory, 119991 Moscow, Russia

6. National Research Centre “Kurchatov Institute”, Akademika Kurchatova pl. 1, 123182 Moscow, Russia

7. Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia

Abstract

This article presents the results of investigations on heterophase polymerization of vinyl monomers in the presence of organosilicon compounds of different structures. On the basis of the detailed study of the kinetic and topochemical regularities of the heterophase polymerization of vinyl monomers, the conditions for the synthesis of polymer suspensions with a narrow particle-size distribution using a one-step method have been determined.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

Reference64 articles.

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