Affiliation:
1. Department of Fiber System Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea
2. School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea
Abstract
Proper design of multifunctional electrocatalyst that are abundantly available on earth, cost-effective and possess excellent activity and electrochemical stability towards oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are required for effective hydrogen generation from water-splitting reaction. In this context, the work herein reports the fabrication of nitrogen-rich porous carbon (NRPC) along with the inclusion of non-noble metal-based catalyst, adopting a simple and scalable methodology. NRPC containing nitrogen and oxygen atoms were synthesized from polybenzoxazine (Pbz) source, and non-noble metal(s) are inserted into the porous carbon surface using hydrothermal process. The structure formation and electrocatalytic activity of neat NRPC and monometallic and bimetallic inclusions (NRPC/Mn, NRPC/Ni and NRPC/NiMn) were analyzed using XRD, Raman, XPS, BET, SEM, TEM and electrochemical measurements. The formation of hierarchical 3D flower-like morphology for NRPC/NiMn was observed in SEM and TEM analyses. Especially, NRPC/NiMn proves to be an efficient electrocatalyst providing an overpotential of 370 mV towards OER and an overpotential of 136 mV towards HER. Moreover, it also shows a lowest Tafel slope of 64 mV dec−1 and exhibits excellent electrochemical stability up to 20 h. The synergistic effect produced by NRPC and bimetallic compounds increases the number of active sites at the electrode/electrolyte interface and thus speeds up the OER process.
Subject
Polymers and Plastics,General Chemistry