Modification of Cellulosic Materials with Boron-Nitrogen Compounds

Abstract

Wood fiber and its products are modified to increase fire and bio-resistance. The best results are achieved by using modifiers that enter into chemical interaction with the hydroxylated substrate, forming the organic matrix of the materials. The purpose of the research described in the article was to study the possibility of using boron-nitrogen compounds to modify cellulose and cellulose-containing materials to improve the performance, bio- and fire-protective properties of construction materials, as well as to optimize the consumption of boron-nitrogen compounds. As a result of the research, it was found that the boron-nitrogen compounds used in the compositions developed here chemically interact with hydroxyl groups at the C6-atom of cellulose. The chemical interaction of boron-nitrogen compounds with cellulose is an inter-crystalline process occurring without destruction of the crystal structure of the substrate since the modifier molecules bind with the more accessible hydroxyl groups of the amorphous regions of cellulose. Thus, surface modification with boron-nitrogen compounds does not result in accelerated aging of cellulose-containing materials and loss of strength but, on the contrary, increases the durability of wooden structures.