Investigating the Mechanical, Thermal, and Crystalline Properties of Raw and Potassium Hydroxide Treated Butea Parviflora Fibers for Green Polymer Composites

Author:

Mohan Abisha1,Priya Retnam Krishna1,Arunachalam Krishna Prakash2ORCID,Avudaiappan Siva345ORCID,Maureira-Carsalade Nelson6ORCID,Roco-Videla Angel7ORCID

Affiliation:

1. PG & Research Department of Physics, Holy Cross College, Nagercoil, Affiliated to Manonmaniam Sundaranar University, Tirunelveli 627012, India

2. Department of Civil Engineering, University College of Engineering Nagercoil, Anna University, Nagercoil 629004, India

3. Departamento de Ingeniería Civil, Universidad de Concepción, Concepción 4070386, Chile

4. Centro Nacional de Excelencia para la Industria de la Madera (CENAMAD), Pontificia Universidad Católica de Chile, Av. Vicuña Mackenna 4860, Santiago 8330024, Chile

5. Department of Physiology, Saveetha Dental College and Hospitals, SIMATS, Chennai 600077, India

6. Departamento de Ingeniería Civil, Universidad Católica de la Santísima Concepción, Concepción 4090541, Chile

7. Facultad de Salud y Ciencias Sociales, Universidad de las Américas, Providencia, Santiago 7500975, Chile

Abstract

The only biotic factor that can satisfy the needs of human species are plants. In order to minimize plastic usage and spread an immediate require of environmental awareness, the globe urges for the development of green composite materials. Natural fibers show good renewability and sustainability and are hence utilized as reinforcements in polymer matrix composites. The present work concerns on the usage of Butea parviflora fiber (BP), a green material, for high end applications. The study throws light upon the characterization of raw and potassium hydroxide (KOH)–treated Butea Parviflora plant, where its physical, structural, morphological, mechanical, and thermal properties are analyzed using the powder XRD, FTIR spectroscopy, FESEM micrographs, tensile testing, Tg-DTA, Thermal conductivity, Chemical composition, and CHNS analysis. The density values of untreated and KOH-treated fibers are 1.238 g/cc and 1.340 g/cc, respectively. The crystallinity index of the treated fiber has significantly increased from 83.63% to 86.03%. The cellulose content of the treated fiber also experienced a substantial increase from 58.50% to 60.72%. Treated fibers exhibited a reduction in both hemicelluloses and wax content. Spectroscopic studies registered varying vibrations of functional groups residing on the fibers. SEM images distinguished specific changes on the raw and treated fiber surfaces. The Availability of elements Carbon, Nitrogen, and Hydrogen were analyzed using the CHNS studies. The tensile strength and modulus of treated fibers has risen to 192.97 MPa and 3.46 Gpa, respectively. Thermal conductivity (K) using Lee’s disc showed a decrement in the K values of alkalized BP. The activation energy Ea lies between 55.95 and 73.15 kJ/mol. The fibers can withstand a good temperature of up to 240 °C, presenting that it can be tuned in for making sustainable composites.

Funder

Vicerrectoria de Investigacion y Desarrollo (VRID) y Direccion de Investigacion y Creacion Artistica DICA

Universidad de Concepción

Centro Nacional de Excelencia para la Industria de la Madera

Pontificia Universidad Católica de Chile

Dirección de Investigación de la Universidad Católica de la Santísima Concepción

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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