Characterization of the Heavy Mineral Suite in a Holocene Beach Placer, Barrytown, New Zealand

Abstract

The placer deposit at Barrytown, New Zealand, has been worked for gold and is known for high levels of ilmenite that has not been exploited. Other heavy minerals are present but have not been well characterized, which is the purpose of this research. Sand grains were separated into the density fractions and the heavier fractions analyzed by laser ablation ICP-MS for elemental composition and by scanning electron microscopy (SEM) EDS in whole grains and polished sections. Grain size distributions were determined from SEM images of polished grain mounts. Elemental associations have been identified with different minerals. A wide range of ore minerals, or potential useful industrial minerals, have been shown to be present largely as individual sand grains. These include gold, ilmenite, garnet, zircon, monazite, allanite, uraninite, thorite, cassiterite, wolframite, scheelite, and columbite. The ilmenite contains many inclusions, consisting of silicates and phosphates and 100–400 ppm Nb. Scandium is found to be present in zircon at 100–600 ppm along with 3000 ppm Y. Monazite is depleted in Eu relative to chondrite and contains Ga and Ge at 1000–3000 ppm. Because the sand grains are mostly individual minerals, it is suggested that separation may be possible using a combination of density, electrostatic and magnetic methods to obtain almost pure mineral fractions. This knowledge should inform decisions on potential exploitation of the resource.