Assessing the Versatility of Bioextraction to Preserve Waterlogged Wood

Author:

Monachon Mathilde1,Pelé-Meziani Charlène2,Ganesan Sathiyanarayanan1,de Weck Sabine3,Moll-Dau Friederike4,Schramm Janet5,Schmidt-Ott Katharina5ORCID,Joseph Edith13ORCID

Affiliation:

1. Laboratory of Technologies for Heritage Materials, Institute of Chemistry, University of Neuchâtel, 2000 Neuchâtel, Switzerland

2. Laboratoire de Conservation-Restauration Arc’Antique, 44300 Nantes, France

3. Haute Ecole Arc Conservation Restauration, University of Applied Sciences and Arts Western Switzerland HES-SO, 2000 Neuchâtel, Switzerland

4. Archaeological Service of Canton Bern, 3001 Bern, Switzerland

5. Swiss National Museum, Collection Center, 8910 Affoltern am Albis, Switzerland

Abstract

An innovative bio method was investigated to extract harmful iron and sulfur species from waterlogged wood samples. The method was compared with a chemical treatment. Both approaches were applied on lacustrine and marine samples, from different wood genera, to evaluate the versatility of the proposed bio method. Non-invasive and non-destructive methods were carried out to investigate both bio-based and chemical treatments. The result was that some wood genera were more affected by the bio approach, with a clear distinction between lacustrine beech and pine against oak and lime wood species. The chemical approach showed potential harm for the wooden structure, with acidic pH values and an increase of maximum water content, both implying degradation of the wood structure. In terms of extraction, no iron or sulfur products were detected by Raman spectroscopy on biologically treated samples, in agreement with extraction rates calculated. It was also suggested that iron bonded to wood was extracted with the chemical approach, and calcium content affected by both approaches.

Funder

Swiss National Science Foundation

Publisher

MDPI AG

Subject

Forestry

Reference85 articles.

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4. Sulfur and iron speciation in recently recovered timbers of the Mary Rose revealed via X-ray absorption spectroscopy;Wetherall;J. Archaeol. Sci.,2008

5. Microbiologically influenced corrosion of archaeological artefacts:Characterisation of iron(II) sulfides by Raman spectroscopy;Saheb;J. Raman Spectrosc.,2010

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