Optimization of a Low-Cost Corona Dielectric-Barrier Discharge Plasma Wastewater Treatment System through Central Composite Design/Response Surface Methodology with Mechanistic and Efficiency Analysis

Abstract

Water pollution, which is intensified by the release of hard-to-degrade pollutants, poses severe threats to ecosystems, human health, and economic development. The existing advanced oxidation processes often involve high operational costs and can potentially result in secondary pollution, highlighting the necessity for innovative and more sustainable solutions. To address these challenges, our study introduces a cost-effective and eco-friendly corona dielectric-barrier discharge for wastewater treatment. Using the central composite design/response surface methodology, a high decolorization rate of 98% of methylene blue (MB) was achieved within 10 min by optimizing parameters such as pH and voltage. Furthermore, the mechanisms underlying the generation of reactive oxygen species through this device were discussed in detail and the degradation pathways of MB were elucidated. Moreover, this device is very energy-efficient, exhibiting a low energy density and electrical energy per order of 0.15 watt/mL and 5.79 kWh/m3/order, respectively. In conclusion, the plasma discharger developed in this study provides a cost-effective and environmentally sustainable solution for dye wastewater treatment. This research contributes significantly to the advancement of sustainable dye wastewater management practices, offering an innovative method that meets both environmental and economic objectives.