Analysis and Prediction of the Leaching Process of Ionic Rare Earth: A Data Mining Study with Scarce Data

Author:

Zhang Zhenyue12,Yang Jing1,Guo Wenda13,Jiang Ling1,Chen Wendou1ORCID,Liu Defeng1ORCID,Wu Hanjun4ORCID,Chi Ruan12

Affiliation:

1. School of Resources and Safety Engineering, Xingfa School of Mining Engineering, Wuhan Institute of Technology, Wuhan 430073, China

2. Key Laboratory for Green Chemical Process, Ministry of Education, Wuhan 430073, China

3. Hubei Xingfa Chemicals Group Co., Ltd., Yichang 443000, China

4. School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China

Abstract

To unveil the impact of each condition variable on the leaching efficiency index during the heap leaching process of rare earth ore and establish a prediction model for leaching conditions and efficiency, common parameters in the heap leaching process of rare earth ore were selected. In addition, the pilot-scale test data were collected over 50 days. Based on the collected data, the Ordinary Least Squares (OLS) linear regression method was used for fitting analysis to determine each variable’s influence on the change in leaching efficiency. The results indicated a linear relationship between the flow rate of the leaching solution and leaching efficiency. In contrast, no obvious linear relationship was observed between other condition variables and leaching efficiency. Spearman’s rank correlation coefficient was calculated to analyze the nonlinear correlation between the abovementioned variables and the leaching efficiency index. The correlation coefficients were found to be −0.78, 0.88, −0.93, −0.53, 0.71, and −0.93 for ammonium content in the leaching agent, pH of the leaching agent, rare earth content, ammonium content in the leaching solution, pH of the leaching solution, and the flow rate of the leaching solution, respectively. This suggests that the flow rate of the leaching solution, rare earth content, and pH of the leaching agent significantly influence leaching efficiency, thus affecting the rare earth leaching efficiency index. Based on the correlation analysis results of leaching conditions and efficiency, a dataset with limited data trained by the common Ordinary Least Squares model, linear regression model, random forest model, and support vector machine regression model was selected to develop a prediction model for the leaching process data. The results indicated that the random forest model had the lowest mean square error of 7.47 among the four models and the coefficient of determination closest to 1 (0.99). This model can effectively analyze and predict condition variables’ data and leaching efficiency index in the heap leaching process of rare earth ore, with a prediction accuracy exceeding 90%, thus providing intelligent guidance for the heap leaching process of rare earth ores.

Funder

National Key Research and Development Program of China

Publisher

MDPI AG

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