Two-Dimensional Nanomaterials for the Removal of Pharmaceuticals from Wastewater: A Critical Review

Abstract

The removal of pharmaceuticals from wastewater is critical due to their considerable risk on ecosystems and human health. Additionally, they are resistant to conventional chemical and biological remediation methods. Two-dimensional nanomaterials are a promising approach to face this challenge due to their combination of high surface areas, high electrical conductivities, and partially optical transparency. This review discusses the state-of-the-art concerning their use as adsorbents, oxidation catalysts or photocatalysts, and electrochemical catalysts for water treatment purposes. The bibliographic search bases upon academic databases including articles published until August 2021. Regarding adsorption, high removal capacities (>200 mg g−1) and short equilibrium times (<30 min) are reported for molybdenum disulfide, metal-organic frameworks, MXenes, and graphene oxide/magnetite nanocomposites, attributed to a strong adsorbate-adsorbent chemical interaction. Concerning photocatalysis, MXenes and carbon nitride heterostructures show enhanced charge carriers separation, favoring the generation of reactive oxygen species to degrade most pharmaceuticals. Peroxymonosulfate activation via pure or photo-assisted catalytic oxidation is promising to completely degrade many compounds in less than 30 min. Future work should be focused on the exploration of greener synthesis methods, regeneration, and recycling at the end-of-life of two-dimensional materials towards their successful large-scale production and application.