Abstract
Nickel(II) complexes with bidentate N,N-α-diimine ligands constitute a broad class of promising catalysts for the synthesis of branched polyethylenes via ethylene homopolymerization. Despite extensive studies devoted to the rational design of new Ni(II) α-diimines with desired catalytic properties, the polymerization mechanism has not been fully rationalized. In contrast to the well-characterized cationic Ni(II) active sites of ethylene polymerization and their precursors, the structure and role of Ni(I) species in the polymerization process continues to be a “black box”. This perspective discusses recent advances in the understanding of the nature and role of monovalent nickel complexes formed in Ni(II) α-diimine-based ethylene polymerization catalyst systems.
Funder
Ministry of Science and Higher Education within the governmental order for Boreskov Institute of Catalysis
Subject
Physical and Theoretical Chemistry,Catalysis
Cited by
6 articles.
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