Author:
Supranovich Vyacheslav I.,Dilman Alexander D.
Abstract
A protocol for the coupling of potassium xanthogenates with α-(trifluoromethyl)styrenes in the presence of triethyl phosphite is reported. The reaction is carried out under blue light irradiation in the presence of organic photocatalyst 3DPAFIPN. The reaction proceeds via formation of alkyl radicals from readily available xanthogenate salts via oxidative desulfurization and cleavage of the carbon–oxygen bond assisted by triethyl phosphite.
Funder
Russian Science Foundation
Subject
Physical and Theoretical Chemistry,Catalysis
Cited by
9 articles.
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