Towards High-Efficiency Photon Trapping in Thin-Film Perovskite Solar Cells Using Etched Fractal Metadevices

Author:

Bărar Ana1ORCID,Maclean Stephen Akwei2,Dănilă Octavian3ORCID,Taylor André D.2

Affiliation:

1. Electronic Technology and Reliability Department, Polytechnic University of Bucharest, 060082 Bucharest, Romania

2. Chemical Engineering Department, Tandon School of Engineering, New York University, Brooklyn, NY 11201, USA

3. Physics Department, Polytechnic University of Bucharest, 060082 Bucharest, Romania

Abstract

Reflective loss is one of the main factors contributing to power conversion efficiency limitation in thin-film perovskite solar cells. This issue has been tackled through several approaches, such as anti-reflective coatings, surface texturing, or superficial light-trapping metastructures. We report detailed simulation-based investigations on the photon trapping capabilities of a standard Methylammonium Lead Iodide (MAPbI3) solar cell, with its top layer conveniently designed as a fractal metadevice, to reach a reflection value R<0.1 in the visible domain. Our results show that, under certain architecture configurations, reflection values below 0.1 are obtained throughout the visible domain. This represents a net improvement when compared to the 0.25 reflection yielded by a reference MAPbI3 having a plane surface, under identical simulation conditions. We also present the minimum architectural requirements of the metadevice by comparing it to simpler structures of the same family and performing a comparative study. Furthermore, the designed metadevice presents low power dissipation and exhibits approximately similar behavior regardless of the incident polarization angle. As a result, the proposed system is a viable candidate for being a standard requirement in obtaining high-efficiency perovskite solar cells.

Funder

Romanian-US Fulbright Commission

New York University

Polytechnic University of Bucharest

Publisher

MDPI AG

Subject

General Materials Science

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