Easy Handling and Cost-Efficient Processing of a Tb3+-MOF: The Emissive Capacity of the Membrane-Immobilized Material, Water Vapour Adsorption and Proton Conductivity

Author:

Echenique-Errandonea EstitxuORCID,Mendes Ricardo FariaORCID,Figueira FlávioORCID,Barbosa Paula,Rojas SaraORCID,Choquesillo-Lazarte DuaneORCID,Cepeda JavierORCID,Ananias DuarteORCID,Figueiredo FilipeORCID,Almeida Paz Filipe A.ORCID,Rodríguez-Diéguez AntonioORCID,Seco José ManuelORCID

Abstract

The development of convenient, non-complicated, and cost-efficient processing techniques for packing low-density MOF powders for industry implementation is essential nowadays. To increase MOFs’ availability in industrial settings, we propose the synthesis of a novel 3D Tb-MOF (1) and a simple and non-expensive method for its immobilization in the form of pellets and membranes in polymethacrylate (PMMA) and polysulphone (PSF). The photoluminescent properties of the processed materials were investigated. To simulate industrial conditions, stability towards temperature and humidity have been explored in the pelletized material. Water-adsorption studies have been carried out in bulk and processed materials, and because of the considerable capacity to adsorb water, proton-conduction studies have been investigated for 1.

Funder

University of the Basque Country

CICECO-Aveiro Institute of Materials

Ministry of Science, Innovation and Universities

Junta de Andalucía

Gobierno Vasco

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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