The Construction of Phosphorus-Doped g-C3N4/Rh-Doped SrTiO3 with Type-II Band Alignment for Efficient Photocatalytic Hydrogen Evolution

Author:

Wang Bin,Li Peng,Hao Hanjing,He Huijie,Cai Hairui,Shang Fanfan,An Bei,Li Xiaoqian,Yang Shengchun

Abstract

It is of great importance to promote charge separation in photocatalysts for enhanced photocatalytic activity under visible light irradiation. In this work, a type-II heterostructured photocatalyst was constructed by compositing phosphorus-doped g-C3N4 (P-CN) and Rh-doped SrTiO3 (Rh-STO) via a thermal calcination treatment. A series of characterizations were conducted to investigate the structure of heterostructured P-CN/Rh-STO. It was found that Rh-STO interacted with in situ generated P atoms from the decomposition of P-CN during the calcination process, thus leading to the formation of heterojunction of P-CN/Rh-STO. Compared with the single component, i.e., P-CN or Rh-STO, the obtained P-CN/Rh-STO showed superior photocatalytic activity to that of both P-CN and Rh-STO due to the effective charge separation across the heterojunction between P-CN and Rh-STO.

Funder

National Science and Technology Major project

China Postdoctoral Science Foundation

Natural Science Foundation of Shaanxi Province

the project of Innovative Team of Shaanxi Province

Shccig-Qinling Program

the China Fundamental Research Funds for the Central Universities, and the World-Class Universities (Disciplines) and the Characteristic Development Guidance Funds for the Central Universities

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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