Identification and Discrimination of Petrol Sources by Nuclear Magnetic Resonance Spectroscopy and Machine Learning in Fire Debris Analysis

Author:

Yankova Yanita1,Cirstea Silvia2,Cole Michael3,Warren John4

Affiliation:

1. Eurofins Forensic Services, 1 Dukes Green Avenue, Feltham TW14 0LR, UK

2. School of Computing and Information Sciences, Anglia Ruskin University, East Road, Cambridge CB1 1PT, UK

3. School of Life Sciences, Anglia Ruskin University, East Road, Cambridge CB1 1PT, UK

4. Jazz Pharma, Unit 840 Broadoak Rd, Sittingbourne ME9 8AG, UK

Abstract

Petrol is considered the most common fire accelerant. However, the identification and classification of petrol sources through the years has proven to be a challenging field in the investigation of fire debris analysis. This research explored the possibility of identifying petrol sources by high-field NMR methods accompanied by ML (machine learning). The automated identification and classification of petrol brands were achieved for first time based on the ML classification model developed in this research. A hierarchical classification model was constructed using local classifiers to categorize neat or weathered petrol into its sources.

Publisher

MDPI AG

Reference21 articles.

1. Analysis of Petroleum Products in Fire Debris Residues by Gas Chromatography: A Literature review;Bumbrah;Arab. J. Forensic Sci. Forensic Med.,2017

2. Identification and Discrimination of Brands of Fuels by Gas Chromatography and Neural Networks Algorithm in Forensic Research;Ugena;J. Anal. Methods Chem.,2016

3. Desa, W. (2012). The Discrimination of Ignitable Liquids and Ignitable Liquid Residues Using Chemometric Analysis. [Ph.D. Thesis, University of Strathclyde].

4. Differentiation of unevaporated gasoline samples according to their brands, by SPME-GC-MS and multivariate statistical analysis;Monfreda;J. Forensic Sci.,2011

5. Detection and Classification of Ignitable Liquid Residues in the Presence of Matrix Interferences by Using Direct Analysis in Real Time Mass Spectrometry;Barnett;J. Forensic Sci.,2019

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