Abstract
Ion implantation technique was employed to introduce iron nanoparticles (Fe NPs) into a carbon precursor polymer with the aim of forming of a graphitic nanostructure through catalytic graphitization by the introduced Fe NPs. A phenolic resin was implanted by 100 keV Fe+ ions with ion fluence of 1 × 1014–1 × 1016 ions/cm2 at ambient temperature under vacuum, and subsequently heat-treated at 800 °C in a nitrogen gas atmosphere. It was found that the particle size of Fe NPs could be controlled in the range of 5–30 nm by the Fe+ ion fluence. Additionally, it was found that a nanosized turbostratic graphite structure with mean interlayer distance of 0.3531 nm, which is consisted of shell-like carbon layers and intricately distorted carbon layers, was formed around the Fe NPs. The ion implantation technique is one of the advantageous ways to introduce size-controlled fine metal NPs which are effective for the formation of graphitic nanostructure from a carbon precursor polymer.
Funder
Japan Society for the Promotion of Science
Subject
Nuclear and High Energy Physics,Atomic and Molecular Physics, and Optics
Cited by
8 articles.
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