Mineralogy and in situ S and Pb isotope characteristics of ore minerals from polymetallic mineralization in the Gierczyn-Przecznica area, SW Poland

Abstract

Chlorite-mica-quartz schist in the Gierczyn-Przecznica area in SW Poland contains polymetallic ores which were the source of tin and cobalt in the past. This mineralogical study revealed the presence of silver-bearing minerals including members of the tetrahedrite (Ag <3 apfu) and freibergite series (3 < Ag < 8 apfu), galena (0.26–1.48 wt.% Ag), and a phase with the chemical composition of Te-rich canfieldite Ag8Sn(S,Te)6. In Przecznica Sn-sulphides are represented by stannite while cobaltite is the most abundant host for cobalt, followed by Co-bearing arsenopyrite. Glaucodot, ullmannite and members of the löllingite-rammelsbergite solid-solution series (Fe,Ni,Co)As2 also contain cobalt but are scarce in the samples. An exposure in the “Psi Grzbiet” area is characterized by the presence of Ag, Ni, Sb and Te minerals accompanied by very small amounts of As-bearing phases (represented by arsenopyrite) while the mineralogical composition in the Przecznica area is characterized by an abundance of As phases and a lack of Sb minerals. Sulphur isotopes of sulphides from Przecznica are heavier than in most deposits related to the Karkonosze Granite intrusion, while their Pb isotope signature in galena suggests an Early Paleozoic pre-Variscan affinity rather than a Variscan one.